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一、丙烯单体 AcrylicMonomers
1、丙烯酸,丙烯酸酯Acrylic Acid,Acrylic Esters
丙烯酸与丙烯酸酯是包含有乙烯基与羧基的单体,具有很高的反应性。因其能作为适合于环境的高机能聚合物和乳胶漆的材料,而受到国际上的广泛关注。
ACRYLIC ACID and ACRYLIC ESTERS, which can be dividedinto vinyl and carboxylgroups, are drawing widespread attention as anenvironmentally sound rawmaterial for producing high-function polymers and asa soluble base for emulsionpaints.
2、丙烯酸 Acrylic Acid
丙烯酸主要用于高吸水性树脂、粘度调节剂、高分子凝聚剂的原材料。此外丙烯酸和丙烯酸酯、丙烯腈、丁二烯、乙酸乙烯酯的共聚物可以在纤维加工等多个领域中使用。
Acrylic acid is used as the raw material for superabsorbentpolymers, viscositymodifiers, flocculants and so on, among its widepossibilties. Copolymers ofacrylic acid, produced for example using acrylicesters, acrylonitriles,butadienes and vinyl acetates, are used for non-wovenfabrics, binders for flockyprocessing and modifiers for fabrics.
3、丙烯酸酯AcrylicAcid
东亚合成拥有丙烯酸甲酯、丙烯酸乙酯、丁基、丙烯酸-2-乙基乙酯这四种丙烯酸酯及数种特殊丙烯酸酯。这些丙烯酸酯单体和共聚物在透明性、光泽、粘着性、耐老化性、柔软性等多个方面具有优良的性质,适合用于丙烯酸纤维、纤维加工、涂料、粘着剂、纸加工、皮革技工、合成橡胶等领域。
Acrylicesters, which include methyl acrylate,ethylacrylate, butyl acrylateand2-ethylhexyl acrylate, are producedby means of esterfication of acrylicacid, and because of their significantperformance such astransparency,gloss,adhesive property and flexibility, the potential applications of acrylicestersare increasing remarkably.Among major applications of acrylic esters are as rawmaterial for acrylicfiber, textile finishes、paints、adhesives、paper finishes、leather finishes and synthetic rubber.
产品名称 | 化学式 | 纯度 | 比重 | 酸度 | 水分 | 色调 | 聚合抑制剂 |
丙烯酸 | CH2=CHCOOH | 99.0min. | — | — | 0.3max | 20max | 200±20 |
用途:吸水性树脂(SAP)、粘度调节剂(Viscosity modifiers)、高分子凝聚剂(Flocculants)、光硬化树脂(Photo-curing resin) | |||||||
80%丙烯酸 | CH2=CHCOOH | 80.0min. | — | — | 20max | 20max | 160±20 |
用途:吸水性树脂(SAP)、粘度调节剂(Viscosity modifiers)、高分子凝聚剂(Flocculants)、光硬化树脂(Photo-curing resin) | |||||||
丙烯酸甲酯 | CH2=CHCOOCH3 | 99.5min | 0.954-0.958 | 0.005max | 0.005max | 10max. | 15±5 |
用途:丙烯纤维、(Acrylic fiber)、纤维加工(Textile finishes)、涂料(Paint)、皮革加工(Leather)、纸加工(Paper) | |||||||
丙烯酸乙酯 | CH2=CHCOOC2H5 | 99.5min. | 0.920-0.924 | 0.005max | 0.05max | 10max | 15 ± 5 |
用途:纤维加工(Textile finishes)、涂料(Paint) | |||||||
丙烯酸丁基 Butyl acrylate | CH2=CHCOOC4H9 | 99.5min. | 0.896-0.901 | 0.005max | 0.05max | 10max | 15 ± 5 |
用途:纤维加工(Textile finishes)、涂料(Paint)、纸加工(Paper)、粘着剂(Adhesives)、皮革(Leather)、橡胶(Rubber) | |||||||
丙烯酸-2-乙基乙酯 2-Ethylhexyl acrylate | CH2=CHCOOCH2 | 99.5min. | 0.882-0.888 | 0.005max | 0.05max. | 10max | 15±5 |
用途:涂料(Paint)、粘着剂(Adhesives)、橡胶(Rubber)、建筑材料(Construction materials) | |||||||
异丁酯 Iso-Butyl acrylate | CH2=CHCOOCH2 | 99.5min. | 0.887-0.892 | 0.005max | 0.05max. | 10max | 100±20 |
用途:涂料(Paint)、粘着剂(Adhesives)、树脂改良剂(Resin improvement) | |||||||
ACRYCS C-1 丙烯酸-2-甲氧基乙酯 2-Methoxyethyl acrylate | CH2=CHCOOCH2 | 99.0min. | 1.013-1.019 | 0.01max | 0.1max | 20max. | 100±10 |
用途:粘着剂(Adhesives)、树脂改良剂(Resin improvement)、橡胶(Rubber) | |||||||
ACRYCS HEA 丙烯酸2-乙基己酯 2-Hydoroxyethyl acrylate | CH2=CHCOOCH2 | 98.0min. | 1.11 | 1max. | 1max | 50max. | 300±30 |
用途:纤维加工(Textile finishes)、热固性涂料(Thermosetting paint)、粘着剂(Adhesives) | |||||||
ACRYCS CHA 2-丙烯酸环己基酯 Cyclohexyl acrylate | CH2=CHCOO | 99.0min. | 0.975-0.985 | 0.03max. | 0.1max. | 20max. | 50±10 |
用途:涂料(Paint)、涂层(Coating) | |||||||
ARON DA 丙烯酸二甲氨基乙酯 Dimethyaminoethyl acrylate | CH2=CHCOOCH2 | 98.0min. | — | — | 0.05max | 40max | 2000±200 |
用途:高分子凝聚剂(Flocculans)、粘着剂(Adhesives)、涂料(Paint)、 助留剂(Retention aid |
二、丙烯类特殊单体Special Acrylic Monomers
1、ARONIX
ARONIX是丙烯类特殊单体与低聚物的商品名称。分为特殊丙烯酸酯、聚氨酯丙烯酸酯及聚酯丙烯酸酯 三种。可使用一种或结合多种ARONIX到UV墨水、UV涂料、UV粘着剂等领域。它还有良好的反应性,可用作架接剂、改良剂。
ARONIX is thebrand name for specific acrylic monomers and oligomers produced byTOAGOSEI.ARONIX is classified roughly into three grades-specialacrylates,urethaneacrylates and polyester acrylates. ARONIX is commonly usedfor UV-curing inks,UV-curing paints, and UV-curing adhesives through single orcombined uses of eachgrade. High reactive disposition of ARONIX can be appliedfor other practicalapplications.
型号 | 化合物名称 | 外观 | 粘度 | 官能基数Function | 固化物 |
M?113 | 壬基酚聚氧乙烯醚丙烯酸酯 | 淡黄色液体 | 85~110/25 ℃ | 1 | ?20 |
特征:固化物Tg值低(-20℃ ) | |||||
M?211B | 双酚A聚氧乙烯醚丙烯酸酯 | 淡黄色液体 | 950~1,350/25 ℃ | 2 | 75 |
特征:固化速度快、皮肤刺激少、硬度高。 | |||||
M?220 | 丙二醇二丙烯酸酯 | 淡黄色液体或褐色液体 | 8~16/25 ℃ | 2 | 90 |
特征:皮肤刺激少、粘度低 | |||||
M?305 | 季戊四醇三丙烯酸酯 | 淡黄色液体 | 180~800/25 ℃ | 3 | > 250 |
特征:含有羟基、固化速度快 | |||||
M?309 | 三羟甲基丙烷三丙烯酸酯 | 淡黄色液体 | 60~110/25 ℃ | 3 | > 250 |
特征:含有羟基、固化速度快 | |||||
M?315 | EO改性异氰脲酸酯丙烯酸酯与丙烯酸酯 | 白色固体 | 600~1,200/50℃ | 3 | > 250 |
特征:蜡型、良好的耐热性 | |||||
M?350 | 三羟甲基丙烷三甲基聚氧乙烯醚丙烯酸酯Trimethylolpropane polyethoxylate triacrylate | 淡黄色透明液体 | 45~65/25 ℃ | 3 | — |
特征:固化速度快 | |||||
M?402 | 二季戊四醇戊-/己-丙烯酸 | 淡黄色液体或固体 | 5,000~7,000/25 ℃ | 5 ~ 6 | > 250 |
特征:固化速度快 | |||||
M?408 | 二(三羟甲基丙烷)四丙烯酸 | 淡黄色液体 | 470~670/25 ℃ | 4 | > 250 |
特征:良好的相容性、反应性 | |||||
M?520 | 改性多元丙烯酸酯低聚物 | 淡黄色液体或固体 | 11,500~16,500/25 ℃ | 5 ~ 6 | — |
特征:含有羟基 | |||||
M?1200 | 聚氨酯丙烯酸酯 | 淡黄色液体 | 120,000~220,000/50℃ | 2 | 35 |
特征:不变黄、对聚氯乙烯有良的粘附性 | |||||
M?5700 | 2-丙烯酸-2-羟基-3-苯氧基丙酯 | 淡黄色液体 | 140~190/25 ℃ | 1 | 17 |
特征:含有羟基、可形成柔软的涂膜 | |||||
M?7100 | 低聚酯丙烯酸酯 | 淡黄色液体或褐色液体 | 8,000~13,500/25 ℃ | > 3 | 105 |
特征:可形成有光泽的涂膜、固化速度快、硬度高。 | |||||
M?8030 | 低聚酯丙烯酸酯 | 淡黄色液体或褐色液体 | 560~960/25 ℃ | > 3 | > 250 |
特征:良好的相容性、耐热性。 | |||||
M?8060 | 低聚酯丙烯酸酯 | 淡黄色液体或褐色液体 | 5,000~12,000/25 ℃ | > 3 | > 250 |
特征:良好的相容性、耐热性。 |
2、MACROMONOMER
作为含有可重合官能基的高分子量单体,可通过与其他单体的聚合而形成少量同聚物的接枝聚合物。 这种接枝聚合物可均衡发挥线型聚合物所没有的各种相对性能,例如软/固性、结晶/非结晶、亲水/疏水性等。这种效果可利用与涂料、成型材料、粘着剂、粘结剂、释放剂等多种用途。
MACROMONOMERis a high molecular weight monomer whose properties allow it to beeasily polymerizedThismaterial can be polymerized with other monomers to form agraft polymer ofextremely low homopolymercontent. Suc h a graf t polymer offers conflictingproperties, such as soft/hard,crystalline/amorphous,hydrophobic/hydrophilicproperties, which cannot beattained with a linear polymer. Thus, applicationofMACROMONOMER can impart evenhigher functions to paints, molding materials,pressure sensitive adhesives,adhesivesand releasing agents.
型号 | 化合物名称 | 外观 | 固含量 | 官能基数 | 分子量 | |
TerminalGroup | Segment | |||||
45%AA?6 | 异丁烯酰基 | 甲基丙烯酸甲酯 | 甲苯溶液 | 45 | 1 | 6,000 |
特征:改善耐候性、光泽、相容性、分散性 | ||||||
AA?6 | 异丁烯酰基 | 甲基丙烯酸甲酯 | 粉末 粉末 | > 97 | 1 | 6,000 |
特征:改善耐候性、光泽、相容性、分散性 | ||||||
AS?6S | 异丁烯酰基 | 苯乙烯 | 甲苯溶液 | 50 | 1 | 6,000 |
特征:改善光泽、相容性、分散性 | ||||||
AS?6 | 异丁烯酰基 | 苯乙烯 | 粉末 粉末 | > 97 | 1 | 6,000 |
特征:改善光泽、相容性、分散性 | ||||||
AN?6S | 异丁烯酰基 | 苯乙烯丙烯腈 | 甲苯溶液 | 51 | 1 | 6,000 |
特征:改善强韧性、密着性、相容性 | ||||||
AB?6 | 异丁烯酰基 | 丙烯酸丁酯 | 粘稠液体 | > 97 | 1 | 6,000 |
特征:柔软性、溶解性、粘着性 |
3、AcrylamidoTertiary Butyl Sulfonic Acid(ATBS®)
ATBS®是一种含有磺基的乙烯单体。其重合体被利用在纤维、凝聚剂、分散剂、颜料分散剂、防垢剂等广泛领域中。
ATBS®有很高的重合性,能够简单地与丙烯腈、丙烯酸、丙烯酸酯、丙烯酰胺等重合。
ATBSis functional vinyl monomer of sulfonic acid group.
ATBSpolymers are widely used in many industrial applications such as textiletreatmentagents, flocculants,pigment dispersants, scaling preventives in watertreatmentsystems and drilling mud additives. Because of its highly-reactivedisposition,ATBS can easily be copolymerized with monomers such as acrylonitrile,acrylicacid,acrylamide and acrylic esters by common radical polymerizationtechniques.
产品名称 | 化合物名称 | 形状 | 分子量 | pH | 融点 |
ATBS® | 2-丙烯酰胺基叔丁基磺酸 | 小颗粒 | 207.24 | 1.4 | 185℃ |
用途:废水处理凝聚剂、比例控制剂、丙烯纤维染色改善剂等。 |
三、丙烯聚合物Acrylic Polymers
1、分散剂Dispersants
我们提供适合于颜料分散稳定剂、水处理中的水锈附着防止剂、钻井挖掘用分散剂、染色剂、洗涤剂等广泛用途的各种类型分散剂。TOAGOSEIproduces many types of acrylic dispersants for specificapplications –dispersion of various pigments used formaking paper and paints, prevention ofscaling in water treatment systems,dispersants for drilling mud,dyeing aidsand detergent builders
类型 | 型号 | 化合物名称 | 固体含量(%) | 粘度(mPa·s) Viscosity | pH | 分子量 |
液体 | Aron A-210 | 聚丙烯酸钠 | 42~44 | 50~200 | 7 ~ 8 | 3,000 |
用途:颜料分散剂、染料、比例控制剂、土木分散剂 | ||||||
Aron A-10SL | 聚丙烯酸 | 39~41 | 40~150 | < 2 | 5,000 | |
用途:颜料分散剂、染料、水锈控制剂、土木分散剂 | ||||||
Aron T-50 | 聚丙烯酸钠 | 41~45 | 500~1,000 | 7 ~ 9 | 6,000 | |
用途:颜料分散剂、染料、水锈控制剂、土木分散剂、洗涤剂 | ||||||
Aron A-30SL | 聚丙烯酸铵 | 39~41 | 50~500 | 7 ~ 9 | 6,000 | |
用途:陶瓷分散剂 | ||||||
Jurymer AC-203 | 聚丙烯酸钠 | 39~41 | 200~600 | 8 ~ 10 | 9,000 | |
用途:水锈控制剂、陶瓷分散剂 | ||||||
Aron A-6114 | 聚丙烯酸铵 | 39~41 | 40~150 | 8 ~ 9 | 10,000 | |
用途:陶瓷分散剂 | ||||||
Aron A-6016A | 磺酸钠共聚物 | 39~41 | 45~85 | 7 ~ 8 | 2,000 | |
用途:比例控制剂、陶瓷分散剂 | ||||||
Aron A-12SL | 磺酸共聚物 | 39~41 | 50~200 | < 1 | 10,000 | |
用途:水锈控制剂、陶瓷分散剂 | ||||||
Aron A-6330 | 聚羧酸钠盐 | 39~41 | 200~500 | 7.5~8.5 | 10,000 | |
用途:颜料分散剂 | ||||||
粉末 | Jurymer AC-10NPD | 聚丙烯酸钠 | > 93 | 100~300 | 8 ~ 10 | 6000 |
用途:颜料分散剂、染料、水锈控制剂、土木分散剂、洗涤剂 | ||||||
Jurymer AC-103AP | 聚丙烯酸钠 | > 93 | 100~400 | 7~9.5 | 7,000 | |
用途:水锈控制剂、陶瓷分散剂 | ||||||
Jurymer AC-10P | 聚丙烯酸 | > 93 | 100~300 | 2.0~3.5 | 9,000 | |
用途:颜料分散剂、染料、水锈控制剂、土木分散剂 |
2、增粘剂Thickeners
我们提供以聚丙烯酸酯为主的丙烯增粘剂,这些增粘剂拥有增粘效果、流动特性、易作业等特征,分为水溶型、乳液型、粉末型三种。这些产品可作为乳胶、涂料、粘结剂、化妆品的增粘剂使用。
Theseare acrylic thickening agents, mainly consists ofsodium polyacrylates,andavailable in many different grades – water soluble,emulsion or powdery – each havingi ts o wn characteristics i n t hickening, f low a nd workability. Theseproducts are usedto thicken latexes,paints, adhesives and cosmetics.
类型T | 型号 | 化合物名称 | 固含量(%) | 粘度(mPa·s) | pH | 分子量 |
液体 | Jurymer AC-10L | 聚丙烯酸 | 39~41 | 1,000~2,000 | 2.0~3.5 | 5万 |
用途:高流动性、稳定性 | ||||||
Aron A-7185 | 聚羧酸钠盐 | 17~19 | 15,000~25,000 | 8 ~ 10 | 50万 | |
用途:高增粘性、保湿性 | ||||||
Jurymer AC-10H | 聚丙烯酸 | 19~21 | 20,000~40,000 | 2.5~3.5 | 80万 | |
用途:高流动性、稳定性 | ||||||
Aron A-20L | 聚丙烯酸钠 | 16~20 | 20,000~50,000 | 8 ~ 10 | 100万 | |
用途:稳定性、易作业 | ||||||
粉末 | Aron A-20P-X | 聚丙烯酸钠 | > 97 | 400~600/30℃ | — | 500万 |
用途:高流动性、高可纺性 | ||||||
乳液 | Aron B-300K | 聚羧酸锌 | 43~45 | 20~100 | 2 ~ 3 | — |
用途:碱中和型增粘剂、低可纺性 | ||||||
Aron A-7075 | 聚羧酸锌 | 19~21 | 5 ~ 50 | 2 ~ 4 | — | |
用途:碱中和型增粘剂、高增粘性 |
4、接着剂
PressureSensitive Adhesives ARONTACK
胶带、薄纸、标签等等日常用品和工业用品都是使用接着剂的产品。本公司的接着剂ARONTACK是以丙烯酸酯为主要原料的丙烯类粘着剂,拥有耐温、透明、耐热老化等优异的特性。我们可以提供乳液型、溶剂型,强粘着力、弱粘着力,自交联型、二液交联型等适合于多种用途与要求的制品。
Productsusing pressure sensitive adhesives are found in various consumer andindustrialproducts such as tapes,labels and seals.“ARONTACK”,a TOAGOSEI pressure sensitive adhesive,is an acrylic material basedmainly onacrylic esters.It has excellent weather resistance, transparency andthermaldegradation resistance. Consumers can choose from among different gradesofARONTACK for their specific uses or property requirements-emulsions orsolvent-based polymers, strong adhesion or weak adhesion types, andself-cross-linkingor two-part crosslinking types.
类型 | 型号Grade | 固含量(%) Nonvolatiles | 粘度 (mPa·s) Viscosity | 接着力 | 球钉 Ball tack | 溶剂 | 用途Uses |
乳液 | HV?C9500 | 62.0~64.0 | 15,000-20,000 | 4.0 | 13 | 水 | 各种标签 |
特征:固体分量大、凝聚力强、金属粘着性好 | |||||||
HV?C9506 | 64.0~66.0 | 20,000-24,000 | 3.6 | 14 | 水 | 行李、邮寄标签 | |
特征:固体分量大、纸箱粘着性好、低温粘着性好。 | |||||||
HV?C9506 | 57.5~59.5 | 5,000-10,000 | 7.0 | 14 | 水 | 各种标签、热敏纸 | |
特征:聚烯粘着性好、热敏纸发色、褪色性好 | |||||||
HV?C3050 | 57.0~59.0 | 5,000-12,000 | 6.5 | 13 | 水 | 各种标签、热敏纸 | |
特征:聚烯粘着性好、曲面粘着性好 | |||||||
HV?C6320 | 63.0~65.0 | 12,000-16,000 | 3.2 | 14 | 水 | 硬胶条 | |
特征:固体分量大、凝聚力强、密封性好 | |||||||
HV?C5166 | 54.0~56.0 | 10,000-15,000 | 6.8 | 14 | 水 | OPP胶带 | |
特征:透明性、密封性好、粘着性强 | |||||||
RP?275 | 52.0~54.0 | 12,000-18,000 | 3.6 | 12 | 水 | 可再生标签 | |
特征:碱性溶液分解性 | |||||||
有机溶剂 Organic solution | S?1511X | 39.0~41.0 | 3,000-6,000 | 5.0 | 15 | 乙酸乙酯/甲苯 | 交卷、纸标签 |
特征:粘着性能均衡良好 | |||||||
S?1511 | 39.0~41.0 | 3,000-5,500 | 5.2 | 15 | 乙酸乙酯 | 交卷、纸标签 | |
特征:粘着性能均衡良好 | |||||||
S?3403 | 39.0~41.0 | 4,500-6,500 | 9.0 | 15 | 甲苯/正己烷Toluene | 双面胶 | |
特征:粘着力强 | |||||||
S?1601 | 29.0~31.0 | 7,000-9,000 | 3.0 | 15 | 甲苯 | 保护膜 | |
特征:可除性好、自交联 | |||||||
S?1616 | 39.0~41.0 | 110-300 | <0.1 | < 2 | 甲基乙基酮 | 保护膜 | |
特征:可除性好、微粘着 |
5、粘合剂Binder
在各种颜料、农药、陶瓷、玻璃纤维、纸浆、无纺布等广泛使用的产品中,我们提供符合各种需求的丙烯类粘合剂制品。
TOAGOSEI markets various types of binders that meetthediversified requirementsstemming from various applications-pigments, agriculturalchemicals、ceramics、glass fibers、paper、non-woven fabrics and so on.
制品名称 | 类型 | 型号 | 固含量(%) Nonvolatiles | 粘度 (mPa·s) Viscosity | Tg | PH | 用途 |
JURYMER | 液体 | AT?210 | 28.5~31.5 | 5,000-15,000 | ? 8 | 7.5~9.5 | 油墨用粘合剂 |
特征:无泡沫、可形成柔软薄膜 | |||||||
AT?510 | 28.5~31.5 | 15,000-35,000 | 28 | 7.5~9.5 | 化妆品用粘合剂 | ||
特征:无泡沫、与颜料混合性良好 | |||||||
AT-613 | 23.5~26.5 | 3,000-7,000 | 76 | 7 ~ 8 | 化妆品用粘合剂、钢板涂料 | ||
特征:无泡沫、抗粘连性 | |||||||
ARON | 乳液 | A?104 | 39.0~41.0 | 300 -1,000 | 45 | 7 ~ 9 | 颜料类涂料(纸、陶瓷)粘合剂 |
特征:耐水、成膜性 | |||||||
NW-400 | 49.0~51.0 | < 500 | ?41 | 5.5~7.5 | 无纺布用黏合剂、陶瓷用粘合剂 | ||
特征:自交联性、再湿润性好、细腻 | |||||||
NW?7060 | 49.0~51.0 | < 500 | 10 | 4 ~ 6 | 无纺布用粘合剂 | ||
特征:自交联性、湿润、再湿润性好 |
6、涂料基材Paint Vehicles
以丙烯树脂为基础的涂料拥有耐气候性、光泽性、透明性等优良特征。其中还分为干燥型、热烧型涂料和耐水性、密着性、防腐蚀性等级别,适合于各种涂层材料的溶剂型、乳液型产品。这些涂料可用作油墨基材、涂料调节剂使用。
Paints based on acrylic resins offer excellent weatherresistance, transparencyand gloss. TOAGOSEI produces solvent-based andemulsion-base products that aresuitable for various paint materials. Further, they havefound broad acceptanceas ink and paint modifiers.
制品名称Product name | 类型 | 型号 | 固含量(%) Nonvolatiles | 粘度 (mPa·s) Viscosity | Tg(℃) | PH(25℃) | 用途 |
JURYMER | 乳液 | ET?410 | 28.5~31.5 | 10~50 | 44 | 7.5~8.5 | 化妆品涂层 |
特征:无泡沫、机械稳定性良好、耐水 | |||||||
SEK?301 | 36.0~40.0 | 100~500 | 18 | 8 ~ 10 | 纸和膜涂层 | ||
特征:无泡沫、自交联性、耐水性纸 | |||||||
ARON | NS?1200(1) | 39.0~41.0 | 60 ~170 | 45 | 7 ~ 9 | 金属、玻璃、塑料用涂层、粘合剂 | |
特征:无泡沫、高密着性(金属、玻璃、塑料) | |||||||
PE?1000 | 36.0~40.0 | < 100 | — | 6.5~8.5 | 地板蜡 | ||
特征:有光泽、密着性强 | |||||||
有机溶剂 | S?1017 | 38.5~41.5 | 1,500~3,500(30 ℃) | 95 | — | 涂料的表面涂层、PVC表面处理剂 | |
特征:强韧的保护膜、有光泽、耐温性好 | |||||||
S?2060 | 23.0~27.0 | 13,000~20,000(30 ℃) | 95 | — | PVC表面处理剂、磁带用黏合剂 | ||
特征:柔软、强韧的保护膜 |
四、特殊聚合物Special Polymers
1、接枝聚合物 SYMAC,RESEDA
Graft polymers SYMAC, RESEDA
我们公司利用大分子单体合成技术与接枝重合技术,提供各种特性化的丙烯接枝聚合物产品。可为同时发挥硅胶与丙烯独有的特性,在SYMAC中使用了能够作为分离性、润滑性的涂层剂。RESEDA拥有优秀的相容性、密着性,可作为树脂增溶剂、分散剂、涂料、涂层、底漆使用。
TOAGOSEI markets various types of unique acrylic graftpolymers based on its ownmacromonomer synthesis and graft polymerizationtechnologies. “SYMAC” isused for various coatings materialsthat make the most of itsgood mold release and lubrication because SYMAC cansimultaneously offer theproperty of silicones and the feature of acrylicresins. “RESEDA” is usedfor compatibility agents, dispersants,paints, coating materials and primersbecause of its high compatibility and cohesiveness.
制品名称 | 聚合物类型 Type of graft polymer | 类型 Type | 型号Grade | 固含量(%) Non-volatiles | 粘度 Viscosity (mPa·s) | 羟值 OH Value (mgKOH/g) | 酸度值 Acid Value (mgKOH/g) | 环氧值 Epoxy Value (KOHmg/g) | 特征 Characte ristics |
SYMAC | 硅树脂类 Silicone graft polymer | 溶剂型 Organic solution | US | 29 | 10~150 | 26 | — | — | 润滑性、分离性、 |
US | 29 | 100~400 | — | 20 | — | ||||
US | 30 | 200~700 | — | 20 | — | ||||
液体 Water solution | US | 30 | 500~3,000 | — | — | — | |||
用途:热敏纸底面涂层、罐头用润滑剂、表面保护涂层、离型纸 | |||||||||
RESEDA | 苯乙烯/丙烯 Styrene/Acryl GP | 溶剂型 Organic solution | GP | 49 | 100~400 | — | — | — | 密着性、相容性 |
用途:塑料涂料 | |||||||||
丙烯/PMMA Acryl/PMMA GP | 粉末 Powder | GP | >99 | — | — | — | 34 | 密着性、相容性 | |
用途:增溶剂、分散剂、涂层 |
2、胶凝剂Gelling agent
胶凝技术被广泛利用于外用膏药基材、化妆品、退烧贴等领域。本公司可提供以丙烯酸聚合物为中心的中和型ARONVIS,交联型JUNLON、RHEOJIC等产品。
Gelling technology is widely applying for poultices、cosmetics、 cooling sheets.TOAGOSEI markets varioustypes of polyacrylates for gelling agent: ARONVIS(partially neutralized)、JUNLON(crosslinked)、RHEOJIC(crosslinked)
制品名称 | 化合物名称 | 类型Type | 型号Grade | 干燥减量(%) | 粘度(mPas) | pH(25℃) | 特征 | 用途 |
ARONVIS | 部分中和聚丙烯酸钠 | 粉末 Powder | AH?105X | <5 | 500-650/20℃, (0.2%水溶液) | 6.0-7.0 | 弱酸性环境中的增粘性、 | 膏状药基材、 |
AH?106X | <5 | 500-650/20℃, (0.2%水溶液) | 5.5-6.5 | 弱酸性环境中的增粘性、 | 膏状药基材、 | |||
聚丙烯酸钠 | SX | <5 | 400-620/20℃, (0.2%水溶液) | 8.0-10.0 | 高增粘性 | 膏状药基材、 | ||
JURYMER | 聚丙烯酸 | AC?10LHP | <5 | 500-1,000/25℃, (10%水溶液) | 2.5-4.0 | 对颜料粘合性良好 | 膏状药基材、各种颜料 | |
RHEOGIC | 交联聚丙烯酸钠 | 260H | <5 | 7,000-13,000/25℃,(0.5%水溶液) | 8.0-9.0 | 低可纺性、触变性 | 化妆品等各种增粘剂 | |
262L | <5 | 1,500-3,000/25℃, (0.5%水溶液) | 8.0-9.0 | 低可纺性、低粘合性凝胶 | 化妆品等各种增粘剂 | |||
JUNLON | 交联聚丙烯酸 | PW?120 | <5 | 8,000-20,000/25℃, (0.2%水溶液) | 2.5-4.0 | 可在极性溶剂、酒精中溶解 | 膏状药基材、 | |
PW?160 | <5 | 25,000-45,000/25℃ (0.2%水溶液) | 3.0-3.8 | 高增粘性、高触变性 | 膏状药基材、 |
五、以UFO技术为基础的无溶剂型丙烯聚合物
Non-solvent Acrylic PolymersBased on UFO Technology
1、ARUFON
ARUFON是以本公司从美国SCJohnson Polymer, Inc.引进的SGO(固体级低聚物)技术为基础开发而成的无溶剂型丙烯聚合物产品总称。SGO技术是以苯乙烯聚合物为中心的组成物在高温、高压环境下进行连续块状重合,从而在短时间内得到100%低分子聚合物的技术。我司利用多年的丙烯聚合物合成经验、改进了SGO技术,开发出了各种Tg及分子量领域中的苯乙烯/丙烯/纯丙烯聚合物。
“ARUFON” is a non-solventacrylicpolymers based on the Solid Grade Oligomer(SGO) technology developed by SC Johnson Polymer, Inc. SGO is a technology to obtain 100% lowmolecular weight polymers ina short time by continuous bulk polymerizationmainly of styrene monomers under high-temperature,high-pressure conditions.TOAGOSEI has improved the SGO technology by the maximumuse of its longexperience in polymerization, based on which the company has developedvariousselections of polymers- styrene/acrylic type and all acrylic type-whichfeaturevarious Tg and narrow molecular weight distribution.
树脂类型 | 型号Grade | 溶解性(40%) Solubility | 组成分类 | 用途 | |||
碱性水 | IPA | 乙酸乙酯 Ethylacetate | 甲苯 | ||||
无官能基树脂 | UP?1000 | — | ○ | ○ | ○ | 纯丙烯 | 黏合剂、密封材料增塑剂、均染剂 Adhesive, Plasticizer for sealant, Leveling agent |
UP?1021 | — | ○ | ○ | ○ | 纯丙烯 | 塑料增塑剂、助流剂Plasticizer and ?ow modi?er for plastics | |
UP?1110 | — | ○ | ○ | ○ | 纯丙烯 | 黏合剂、密封材料增塑剂、均染剂 Adhesive, Plasticizer for sealant, Coatings and plastics | |
含羟基树脂 | UH?2000 | — | ○ | ○ | ○ | 纯丙烯 | 黏合剂、密封材料增塑剂 Adhesive, Polyol for sealant |
UH?2170 | — | ○ | ○ | ○ | 苯丙 Styrene-Acryl | 高固体涂料、粉末涂料 | |
含羧基树脂 | UC?3000 | ○ | △ | ○ | ○ | 纯丙烯 | 颜料分散剂、涂装材料改质剂、表面施胶机 |
含羧基和长链烷基树脂 | UF?5022 | ○ | ○ | ○ | ○ | 苯丙 Styrene-Acryl | 颜料分散剂、涂装材料改质剂、表面施胶机 |
含环氧基树脂 | UG?4010 | — | ○ | ○ | ○ | 纯丙烯 | 聚酯纤维改质剂、反应性可塑剂 |
UG?4035 | — | ○ | ○ | ○ | 苯丙 Styrene-Acryl | 聚酯纤维改质剂、加工性改良剂、增溶剂 | |
UG?4070 | — | ○ | ○ | ○ | 苯丙 Styrene-Acryl | 聚酯纤维改质剂、加工性改良剂、增溶剂 | |
含甲基树脂 | US?6100 | — | ○ | ○ | ○ | 纯丙烯 | 黏合剂、密封材料增塑剂 |
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